Solidity of viscous liquids

被引:55
作者
Dyre, JC [1 ]
机构
[1] Roskilde Univ, Dept Math & Phys, IMFUFA, DK-4000 Roskilde, Denmark
关键词
D O I
10.1103/PhysRevE.59.2458
中图分类号
O35 [流体力学]; O53 [等离子体物理学];
学科分类号
070204 ; 080103 ; 080704 ;
摘要
Recent NMR experiments on supercooled toluene and glycerol by Hinze and Bohmer show that small rotation angles dominate with only a few large molecular rotations. These results are here interpreted by assuming that viscous liquids are solidlike on short length-scales. A characteristic length, the "solidity length,'' separates solidlike behavior from liquidlike behavior.
引用
收藏
页码:2458 / 2459
页数:2
相关论文
共 32 条
[1]   Growing length scale related to the solidlike behavior in a supercooled liquid [J].
Ahluwalia, R ;
Das, SP .
PHYSICAL REVIEW E, 1998, 57 (05) :5771-5774
[2]   PERSPECTIVE ON THE GLASS-TRANSITION [J].
ANGELL, CA .
JOURNAL OF PHYSICS AND CHEMISTRY OF SOLIDS, 1988, 49 (08) :863-871
[3]   RELAXATION IN LIQUIDS, POLYMERS AND PLASTIC CRYSTALS - STRONG FRAGILE PATTERNS AND PROBLEMS [J].
ANGELL, CA .
JOURNAL OF NON-CRYSTALLINE SOLIDS, 1991, 131 :13-31
[4]   FORMATION OF GLASSES FROM LIQUIDS AND BIOPOLYMERS [J].
ANGELL, CA .
SCIENCE, 1995, 267 (5206) :1924-1935
[5]   Dynamic heterogeneity in supercooled ortho-terphenyl studied by multidimensional deuteron NMR [J].
Bohmer, R ;
Hinze, G ;
Diezemann, G ;
Geil, B ;
Sillescu, H .
EUROPHYSICS LETTERS, 1996, 36 (01) :55-60
[6]   Methods In The Analysis Of Mobile Robots Behavior In Unstructured Environment [J].
Mondoc, Alina ;
Dolga, Valer ;
Gorie, Nina .
9TH INTERNATIONAL CONFERENCE ON MATHEMATICAL PROBLEMS IN ENGINEERING, AEROSPACE AND SCIENCES (ICNPAA 2012), 2012, 1493 :661-665
[7]  
Brawer S., 1985, Relaxation in Viscous Liquids and Glasses
[8]   NON-ARRHENIUS RESPONSE OF GLASS-FORMING LIQUIDS [J].
CHAMBERLIN, RV .
PHYSICAL REVIEW B, 1993, 48 (21) :15638-15645
[9]   DETERMINATION OF THE FREQUENCY-DEPENDENT BULK MODULUS OF GLYCEROL USING A PIEZOELECTRIC SPHERICAL-SHELL [J].
CHRISTENSEN, T ;
OLSEN, NB .
PHYSICAL REVIEW B, 1994, 49 (21) :15396-15399
[10]   HOW DO MOLECULES MOVE NEAR T-G - MOLECULAR ROTATION OF 6 PROBES IN O-TERPHENYL ACROSS 14 DECADES IN TIME [J].
CICERONE, MT ;
BLACKBURN, FR ;
EDIGER, MD .
JOURNAL OF CHEMICAL PHYSICS, 1995, 102 (01) :471-479