Medium-ring diphosphines: synthesis and transannular chemistry

被引：22

作者：

Alder, RW ^{[1
]}

Read, D ^{[1
]}

机构：

[1] Univ Bristol, Sch Chem, Bristol BS8 1TS, Avon, England

来源：

COORDINATION CHEMISTRY REVIEWS | 1998年 / 176卷

基金：

英国工程与自然科学研究理事会;

关键词：

medium-rings; diphosphines;

D O I：

10.1016/S0010-8545(98)00114-3

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Medium-ring diphosphines offer unique opportunities to study the interactions between phosphorus atoms. In addition, monocyclic medium-ring diphosphines may be very useful ligands in transition metal complexes. A number of useful synthetic routes to these compounds have been developed, but further efforts in this direction might be rewarding. (C) 1998 Elsevier Science S.A. All rights reserved.

引用

页码：113 / 133

页数：21

共 75 条

[1] A stereoselective route to medium-ring cis-1,n-dialkyl-1,n-diphosphacycloalkanes [J].

Alder, RW ;

Ellis, DD ;

Hogg, JK ;

Martin, A ;

Orpen, AG ;

Taylor, PN .

CHEMICAL COMMUNICATIONS, 1996, (04) :537-538

[2] MEDIUM-RING BICYCLIC COMPOUNDS AND INTRABRIDGEHEAD CHEMISTRY [J].

ALDER, RW .

ACCOUNTS OF CHEMICAL RESEARCH, 1983, 16 (09) :321-327

[3] INTRABRIDGEHEAD CHEMISTRY [J].

ALDER, RW .

TETRAHEDRON, 1990, 46 (03) :683-713

[4] Medium-ring diphosphines from diphosphabicyclo[k.l.0]alkanes:: stereoselective syntheses, structure and properties [J].

Alder, RW ;

Canter, C ;

Gil, M ;

Gleiter, R ;

Harris, CJ ;

Harris, SE ;

Lange, H ;

Orpen, AG ;

Taylor, PN .

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1, 1998, (10) :1643-1655

[5] SYNTHESES OF MEDIUM-RING 1,K+2-DIAZABICYCLO[KLM]ALKANES BY REDUCTIVE CLEAVAGE OF HYDRAZINUM DICATIONS [J].

ALDER, RW ;

SESSIONS, RB ;

MELLOR, JM ;

RAWLINS, MF .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1977, (21) :747-748

[6] 1,6-DIAZABICYCLO[4.4.4]TETRADECANE AND ITS OXIDIZED IONS [J].

ALDER, RW ;

SESSIONS, RB .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1979, 101 (13) :3651-3652

[7] THE PREPARATION AND REACTIONS OF 1,6-DIPHOSPHATRICYCLO[4.4.4.0]TETRADECANEDIIUM DITRIFLUOROMETHANESULFONATE [J].

ALDER, RW ;

GANTER, C ;

HARRIS, CJ ;

ORPEN, AG .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1992, (17) :1172-1174

[8] PROTON AFFINITIES AND IONIZATION ENERGIES OF BICYCLIC AMINES AND DIAMINES - THE EFFECTS OF RING STRAIN AND OF 3-ELECTRON SIGMA-BONDING [J].

ALDER, RW ;

ARROWSMITH, RJ ;

CASSON, A ;

SESSIONS, RB ;

HEILBRONNER, E ;

KOVAC, B ;

HUBER, H ;

TAAGEPERA, M .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1981, 103 (20) :6137-6142

[9] STRUCTURES OF THE RADICAL CATION AND DICATION FROM OXIDATION OF 1,6-DIAZABICYCLO[4.4.4]TETRADECANE [J].

ALDER, RW ;

ORPEN, AG ;

WHITE, JM .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1985, (14) :949-951

[10] REDUCTIVE CLEAVAGE OF PROPELLANE-TYPE HYDRAZINIUM DICATIONS AS A ROUTE TO MEDIUM-SIZED RING BICYCLIC DIAMINES WITH BRIDGEHEAD NITROGEN-ATOMS [J].

ALDER, RW ;

SESSIONS, RB ;

BENNET, AJ ;

MOSS, RE .

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1, 1982, (02) :603-609

← 1 2 3 4 5 6 7 8 →