Amphicatalytic polymerization: Synthesis of stereomultiblock poly(methyl methacrylate) with diastereospecific ion pairs

被引：52

作者：

Chen, EYX ^{[1
]}

Cooney, MJ ^{[1
]}

机构：

[1] Colorado State Univ, Dept Chem, Ft Collins, CO 80523 USA

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2003年 / 125卷 / 24期

关键词：

D O I：

10.1021/ja035261y

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Diastereospecific ion pairs consisting of isospecific transition-metal cations and syndiospecific main-group anions promote what is termed amphicatalytic polymerization of MMA, producing PMMA with isotactic-b-syndiotactic stereomultiblock microstructures. Copyright © 2003 American Chemical Society.

引用

页码：7150 / 7151

页数：2

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