Electrochemical transformation of cyanoacetic ester and alkylidenecyanoacetic esters into 3-substituted 1,2-dicyanocyclopropane-1,2-dicarboxylates

被引：17

作者：

Elinson, MN ^{[1
]}

Feducovich, SK ^{[1
]}

Bushuev, SG ^{[1
]}

Pashchenko, DV ^{[1
]}

Nikishin, GI ^{[1
]}

机构：

[1] Russian Acad Sci, ND Zelinskii Organ Chem Inst, Moscow 117913, Russia

来源：

RUSSIAN CHEMICAL BULLETIN | 1998年 / 47卷 / 06期

基金：

俄罗斯基础研究基金会;

关键词：

electrolysis; cyanoacetic ester; alkylidenecyanoacetic esters; mediators; 3-substituted 1,2-dicyanocyclopropane-1,2-dicarboxylates;

D O I：

10.1007/BF02503485

中图分类号：

O6 [化学];

学科分类号：

0703 [化学];

摘要：

Electrolysis of cyanoacetic ester and alkylidenecyanoacetic esters in an undivided cell in the presence of mediator; (alkali metal halides) gives rise to 3-substituted 1,2-dicyanocyclopropane-1,2 dicarboxylates in 60-95% yields.

引用

页码：1133 / 1136

页数：4

共 12 条

[1]

The chemistry of the three-carbon system Part II Tautomeric nitriles and cyano-esters [J].

Birch, SF ;

Kon, GAR .

JOURNAL OF THE CHEMICAL SOCIETY, 1923, 123 :2440-2448

[2]

BONAVENT G, 1964, B SOC CHIM FR, P2462

[3]

SYNTHESIS OF OPTICALLY-ACTIVE COMPOUNDS - A LARGE-SCALE PERSPECTIVE [J].

CROSBY, J .

TETRAHEDRON, 1991, 47 (27) :4789-4846

[4]

Elinson MN, 1998, MENDELEEV COMMUN, V8, P15

[5]

ELINSON MN, 1993, MENDELEEV COMMUN, P191

[6]

JONCZYK A, 1976, SYNTHESIS-STUTTGART, P387

[7]

KIM JC, 1969, J CHEM SOC C, P2409

[8]

KRYSHTAL GV, 1980, B ACAD SCI USSR DCS, V29

[9]

LEMENN JC, 1991, CAN J CHEM, V69, P761

[10]

CYCLOCONDENSATION REACTIONS FROM ELECTROGENERATED HALOMALONATE CARBANIONS COMPARED REACTIVITY OF BROMO AND CHLORO ANIONS AND INFLUENCE OF THE SUPPORTING-ELECTROLYTE CATION [J].

LEMENN, JC ;

SARRAZIN, J ;

TALLEC, A .

ELECTROCHIMICA ACTA, 1990, 35 (02) :563-566

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