Femtosecond relaxation of 2-amino-7-nitrofluorene in acetonitrile: Observation of the oscillatory contribution to the solvent response

被引：70

作者：

Ruthmann, J

Kovalenko, SA

Ernsting, NP

Ouw, D

机构：

[1] Humboldt Univ, Inst Phys & Theoret Chem, D-10117 Berlin, Germany

[2] Max Planck Inst Biophys Chem, D-37070 Gottingen, Germany

来源：

JOURNAL OF CHEMICAL PHYSICS | 1998年 / 109卷 / 13期

关键词：

D O I：

10.1063/1.477164

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Transient absorption measurements of aminonitrofluorene in acetonitrile reveal for the first time an oscillatory behavior in the dynamic Stokes shift of stimulated emission. The measured relaxation curve for the maximum of the stimulated emission band is in excellent agreement with the solvation correlation function C(t) obtained from the simple continuum theory of dipolar solvation. (C) 1998 American Institute of Physics. [S0021-9606(98)50637-X].

引用

页码：5466 / 5468

页数：3

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