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Nonaqueous synthesis of CdS nanorod semiconductor

被引：342
作者：
Li, YD [1 ]
Liao, HW
Ding, Y
Qian, YT
Yang, L
Zhou, GE
机构：
[1] Univ Sci & Technol China, Struct Res Lab, Anhua 230026, Peoples R China
[2] Univ Sci & Technol China, Dept Chem, Anhua 230026, Peoples R China
来源：
CHEMISTRY OF MATERIALS | 1998年 / 10卷 / 09期
关键词：
D O I：
10.1021/cm970789l
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
A solvent-coordinating molecular template mechanism to synthesize one-dimensional nanostructure CdS was speculated in the equation below. The solvent molecule ethylenediamine plays an important role in controlling nucleation and growth of the CdS nanorod. As a bidentate ligand, the ethylenediamine molecule may react with cadmium to form relatively stable complexes. Under appropriate solvothermal conditions (above 120 degrees C) the complexes are unstable and may be connected by sulfur to form one-dimensional CdS nanorods.
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页码：2301 / +
页数：4
相关论文
共 58 条
  • [1] THE QUANTUM-MECHANICS OF LARGER SEMICONDUCTOR CLUSTERS (QUANTUM DOTS)
    BAWENDI, MG
    STEIGERWALD, ML
    BRUS, LE
    [J]. ANNUAL REVIEW OF PHYSICAL CHEMISTRY, 1990, 41 : 477 - 496
  • [2] CRYSTALLIZATION OF AN INORGANIC PHASE CONTROLLED BY A POLYMER MATRIX
    BIANCONI, PA
    LIN, J
    STRZELECKI, AR
    [J]. NATURE, 1991, 349 (6307) : 315 - 317
  • [3] BIEDERMANN W, 1948, CHIMIA, V2, P1
  • [4] CONJUGATED POLYMER ELECTROLUMINESCENCE
    BRADLEY, DDC
    [J]. SYNTHETIC METALS, 1993, 54 (1-3) : 401 - 415
  • [5] Semiconducting superlattices templated by molecular assemblies
    Braun, PV
    Osenar, P
    Stupp, SI
    [J]. NATURE, 1996, 380 (6572) : 325 - 328
  • [6] QUANTUM CRYSTALLITES AND NONLINEAR OPTICS
    BRUS, L
    [J]. APPLIED PHYSICS A-MATERIALS SCIENCE & PROCESSING, 1991, 53 (06): : 465 - 474
  • [7] CHEMICAL TUNING OF ELECTROLUMINESCENT COPOLYMERS TO IMPROVE EMISSION EFFICIENCIES AND ALLOW PATTERNING
    BURN, PL
    HOLMES, AB
    KRAFT, A
    BRADLEY, DDC
    BROWN, AR
    FRIEND, RH
    GYMER, RW
    [J]. NATURE, 1992, 356 (6364) : 47 - 49
  • [8] SYNTHETIC AND BIOLOGICAL COMPOSITES FORMED BY INSITU PRECIPITATION
    CALVERT, P
    MANN, S
    [J]. JOURNAL OF MATERIALS SCIENCE, 1988, 23 (11) : 3801 - 3815
  • [9] CHANG W, 1994, NANOSTRUCT MATER, V4, P507, DOI 10.1016/0965-9773(94)90058-2
  • [10] Size dependence of structural metastability in semiconductor nanocrystals
    Chen, CC
    Herhold, AB
    Johnson, CS
    Alivisatos, AP
    [J]. SCIENCE, 1997, 276 (5311) : 398 - 401
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