Dinitrogen tetraoxide complexes of iron(III) and copper(II) as efficient and mild reagents for oxidation of hydroxy compounds

被引：40

作者：

Iranpoor, N ^{[1
]}

Firouzabadi, H ^{[1
]}

Zolfigol, MA ^{[1
]}

机构：

[1] Shiraz Univ, Dept Chem, Shiraz 71454, Iran

来源：

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN | 1998年 / 71卷 / 04期

关键词：

D O I：

10.1246/bcsj.71.905

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Fe(NO3)(3) . 1.5N(2)O(4) is a highly efficient reagent for the oxidation of various classes of hydroxy compounds in dichloromethane at room temperature, or in the absence of solvent. Cu(NO3)(2) . N2O4 oxidizes different hydroxy compounds in refluxing carbon tetrachloride and is a highly selective reagent for oxidation of primary benzylic alcohols in refluxing EtOAc.

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页码：905 / 908

页数：4

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