N-trimethylsilyl-bis(trifluoromethanesulfonyl)imide: a better carbonyl activator than trimethylsilyl triflate.

被引：114

作者：

Mathieu, B ^{[1
]}

Ghosez, L ^{[1
]}

机构：

[1] UNIV CATHOLIQUE LOUVAIN,LAB CHIM ORGAN & SYNTH,B-1348 LOUVAIN,BELGIUM

来源：

TETRAHEDRON LETTERS | 1997年 / 38卷 / 31期

关键词：

D O I：

10.1016/S0040-4039(97)01208-2

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

N-trimethylsilyl-bis(trifluoromethanesulfonyl)imide (TMSNTf2) was readily prepared from allyltrimethylsilane and bis(trifluoromethanesulfonyl)imide. It was shown to complex carbonyl groups much more effectively than trimethylsilyl triflate. As a result, TMSNTF2 was found to be superior to TMSOTf as a catalyst for the Diels-Alder reaction of methyl acrylate with various dienes. (C) 1997 Elsevier Science Ltd.

引用

页码：5497 / 5500

页数：4

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