Superb fluoride and arsenic removal performance of highly ordered mesoporous aluminas

被引:126
作者
Li, Wei [1 ,2 ]
Cao, Chang-Yan [1 ]
Wu, Ling-Yan [1 ,2 ]
Ge, Mao-Fa [1 ]
Song, Wei-Guo [1 ]
机构
[1] Chinese Acad Sci, Key Lab Mol Nanostruct & Nanotechnol, Inst Chem, Beijing Natl Lab Mol Sci BNLMS, Beijing 100190, Peoples R China
[2] Chinese Acad Sci, Grad Univ, Beijing 100049, Peoples R China
基金
中国国家自然科学基金;
关键词
Mesoporous aluminas; Fluoride; Arsenic; Adsorption; Water treatment; DRINKING-WATER; AQUEOUS-SOLUTION; METAL-OXIDES; NANO-SCALE; ADSORPTION; EQUILIBRIUM; COPRECIPITATION; REACTIVITY; MINERALOGY; ION;
D O I
10.1016/j.jhazmat.2011.10.025
中图分类号
X [环境科学、安全科学];
学科分类号
08 ; 0830 ;
摘要
Highly ordered mesoporous aluminas and calcium-doped aluminas were synthesized through a facile and reproducible method. Their fluoride adsorption characteristics, including adsorption isotherms, adsorption kinetics, the effect of pH and co-existing anions were investigated. These materials exhibited strong affinity to fluoride ions and extremely high defluoridation capacities. The highest defluoridation capacity value reached 450 mg/g. These materials also showed superb arsenic removal ability. 1 g of mesoporous alumina was able to treat 200 kg of arsenic contaminated water with a pH value of 7, reducing the concentration of arsenate from 100 ppb to 1 ppb. (C) 2011 Elsevier B.V. All rights reserved.
引用
收藏
页码:143 / 150
页数:8
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