The Effect of Steam on the Fast Carbonation Reaction Rates of CaO

被引：76

作者：

Arias, B. ^{[1
]}

Grasa, G. ^{[2
]}

Abanades, J. C. ^{[1
]}

Manovic, V. ^{[3
]}

Anthony, E. J. ^{[3
]}

机构：

[1] CSIC, Inst Nacl Carbon, Oviedo 33011, Spain

[2] CSIC, Inst Carboquim, Zaragoza 50015, Spain

[3] Nat Resources Canada, CanmetENERGY, Ottawa, ON K1A 1M1, Canada

来源：

INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH | 2012年 / 51卷 / 05期

关键词：

CO2 CAPTURE CAPACITY; PRODUCT LAYER; CARBONATION/CALCINATION; SORBENTS; PARTICLES;

D O I：

10.1021/ie202648p

中图分类号：

TQ [化学工业];

学科分类号：

081705 [工业催化];

摘要：

Postcombustion CO, capture using calcium looping (CaL) is a rapidly developing technology based on the reaction between CaO and CO2. The influence of the presence of steam in the flue gas on the carbonation reaction has been barely studied in the literature. Experiments using a thermogravimetric analyzer (TGA) were carried out to study the effect of steam over the very short reaction time where the carbonation reaction takes place under the kinetic-controlled regime. A simple reaction particle model is applied to interpret the results obtained and to derive reaction rate constants and support the quantitative discussion on steam effects. Results obtained in this work indicate that steam has no influence on the reaction rate constant.

引用

页码：2478 / 2482

页数：5

共 29 条

[1]

Conversion limits in the reaction of CO2 with lime [J].