Metal-Induced Phosphorescence in (Pentafluorophenyl)gold(III) Complexes

被引：13

作者：

Bojan, Vilma R. ^{[1
]}

Lopez-de-Luzuriaga, Jose M. ^{[1
]}

Manso, Elena ^{[1
]}

Monge, Miguel ^{[1
]}

Elena Olmos, M. ^{[1
]}

机构：

[1] Univ La Rioja, Dept Quim, UA CSIC, Grp Sintesis Quim La Rioja, Logrono 26004, Spain

来源：

ORGANOMETALLICS | 2011年 / 30卷 / 17期

关键词：

C-N-C; PHOTOPHYSICS; COORDINATION;

D O I：

10.1021/om200537w

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The complexes [Au(C6F5)(2)(4-X-Py)(2)]ClO4 (X = CN (1), H (2), CH3 (3)) and [Au(C6F5)Cl-2(4-X-Py)] (X = CN (4), H (5), CH3 (6)) have been synthesized. The crystal structure of complexes 1, 3.0.5Et(2)O, 4, and 5 have been determined by X-ray diffraction methods. The photophysical behavior of all complexes has been studied experimentally through UV/vis spectroscopy and photoluminescence studies. TD-DFT calculations and full optimization of the ground state (S-0) and lowest triplet excited state (T-1) have been carried out in order to assign the photophysical properties of the complexes.

引用

页码：4486 / 4489

页数：4

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