Solution and mechanochemical syntheses, and spectroscopic and structural studies in the silver(I) (bi-)carbonate: triphenylphosphine system

被引：31

作者：

Bowmaker, Graham A. ^{[1
]}

Effendy ^{[2
,3
]}

Hanna, John V. ^{[4
]}

Healy, Peter C. ^{[5
]}

King, Scott P. ^{[4
]}

Pettinari, Claudio ^{[6
]}

Skelton, Brian W. ^{[2
]}

White, Allan H. ^{[2
]}

机构：

[1] Univ Auckland, Sch Chem Sci, Auckland 1, New Zealand

[2] Univ Western Australia, Sch Biomed Biomol & Chem Sci, Crawley, WA 6009, Australia

[3] FMIPA Univ Negeri Malang, Malang 65145, Indonesia

[4] Univ Warwick, Dept Phys, Coventry CV4 7AL, W Midlands, England

[5] Griffith Univ, Sch Biomol & Phys Sci, Nathan, Qld 4111, Australia

[6] Univ Camerino, Sch Pharm, I-62032 Camerino Mc, Italy

来源：

DALTON TRANSACTIONS | 2011年 / 40卷 / 27期

基金：

英国工程与自然科学研究理事会;

关键词：

INFRARED-SPECTRA; COORDINATION NETWORKS; CRYSTAL-STRUCTURES; NMR-SPECTRA; COMPLEXES; COPPER(I); BICARBONATE; CARBONATES; ADDUCTS; SOLIDS;

D O I：

10.1039/c1dt10416k

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Syntheses of a number of adducts of silver(I) (bi-)carbonate with triphenylphosphine, both mechanochemically, and from solution, are described, together with their infra-red spectra, P-31 CP MAS NMR and crystal structures. Ag(HCO3):PPh3 (1 : 4) has been isolated in the ionic form [Ag(PPh3)(4)(HCO3)center dot 2EtOH center dot 3H(2)O. Ag2CO3:PPh3 (1 : 4) forms a binuclear neutral molecule [(Ph3P)(2)Ag(O,mu-O'center dot CO)Ag(PPh3)(2)](center dot 2H(2)O), while Ag(HCO3):PPh3 (1 : 2) has been isolated in both mononuclear and binuclear forms: [(Ph3P)(2)Ag(O2COH)] and [(Ph3P)(2)Ag(mu-O center dot CO center dot OH)(2)Ag(PPh3)(2)] (both unsolvated). A more convenient method for the preparation of the previously reported copper(I) complex [(Ph-3P)(2)Cu(HCO3)] is also reported.

引用

页码：7210 / 7218

页数：9

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