Effects of atmospheric boundary layer mixing representations on vertical distribution of passive and reactive tracers

A one-dimensional chemistry-boundary layer model was used to study the effects of differing representations of atmospheric boundary layer (ABL) processes on simulated concentrations of passive and chemically reactive tracers. Two local- and two nonlocal-closure ABL schemes were used to perform numerical simulations during convective conditions in the ABL. Observational data from the First International Satellite Land Surface Climatology Project (ISLSCP) Field Experiment (FIFE) were used to provide initial meteorological conditions while representative chemical concentrations and surface and elevated emission rates were used to provide initial chemical conditions and chemical sources to the one-dimensional model. Two sets of numerical simulations were performed using the four ABL schemes. The first set simulated bottom-to-top mixing characteristics, and the second set simulated top-to-bottom mixing characteristics. Model simulations were performed for 12h starting from 0700LT 11 July 1987. Our analysis indicate that the simulated concentrations of both passive and reactive chemical species were sensitive to the type of ABL scheme used to represent turbulent mixing processes. Characteristic features associated with each scheme (e.g., growth and intensity of mixing in the ABL) contributed to the differences among the simulated species concentrations. For some of the chemical species these differences were large, particularly in the surface layer and in the interfacial layers of the ABL. Zn turn, differences caused by the differing mixing representations resulted in different chemical production/destruction rates. As a consequence, the simulated species concentrations differed among the simulations. We also found that chemical species concentrations were more sensitive to the type of ABL scheme in the bottom-to-top mixing simulations than in the top-to-bottom simulations.