Reaction of platinum acetate with phosphines and molecular structure of trans-[Pt(OAc)2(PPh3)2]

被引：32

作者：

Basato, M

Biffis, A

Martinati, G

Tubaro, C

Venzo, A

Ganis, P

Benetollo, F

机构：

[1] Univ Padua, Dipartimento Chim Inorgan Metallorgan & Anali, I-35131 Padua, Italy

[2] CNR, ISTM, I-35131 Padua, Italy

[3] CNR, ICIS, I-35127 Padua, Italy

来源：

INORGANICA CHIMICA ACTA | 2003年 / 355卷

关键词：

platinum acetate; platinum(II) complexes; phosphino complexes; acetato complexes; trans complexes;

D O I：

10.1016/S0020-1693(03)00314-1

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

An improved synthesis of platinum acetate is reported in detail. This tetrameric complex reacts with PPh3 or P-n-BU3 at room temperature to give the thermodynamically unstable bis-substituted trans-[Pt(OAc)(2)L-2] complexes, which are not easily accessible via other routes. The structure of the new compound trans-[Pt(OAc)(2)(PPh3)(2)] has been determined by X-ray analysis. (C) 2003 Elsevier B.V. All rights reserved.

引用

页码：399 / 403

页数：5

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