Titanacyclobutane synthesis by radical alkylation of substituted allyl complexes. The use of electron-rich bis(2-piperidinoindenyl)titanocene(III) complexes to control allyl ligand reactivity

被引：26

作者：

Carter, CAG ^{[1
]}

McDonald, R ^{[1
]}

Stryker, JM ^{[1
]}

机构：

[1] Univ Alberta, Dept Chem, Structure Determinat Lab, Edmonton, AB T6G 2G2, Canada

来源：

ORGANOMETALLICS | 1999年 / 18卷 / 05期

关键词：

D O I：

10.1021/om980883r

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

In contrast to reactions of the bis(pentamethylcyclopentadienyl)titanium system, substituted allyl complexes of the electron-rich bis(2-piperidinoindenyl)titanium(III) template are converted to 2,3-disubstituted titanacyclobutane complexes by free radical alkylation at the allyl central carbon.

引用

页码：820 / 822

页数：3

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