Solid-state NMR study of poly(ε-caprolactone)/clay nanocomposites

被引:11
作者
Calberg, C
Jérôme, R
Grandjean, J [1 ]
机构
[1] Univ Liege, Inst Chem B6a, COSM, B-4000 Liege, Belgium
[2] Univ Liege, Inst Chem B6a, CERM, B-4000 Liege, Belgium
关键词
D O I
10.1021/la030369c
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The NMR relaxation parameters of poly(ε-caprolactone)/clay nanocomposites prepared by melt intercalation and in situ polymerization were studied. It was confirmed that these materials can be used to define the abilities and limits of NMR relaxation parameters.
引用
收藏
页码:2039 / 2041
页数:3
相关论文
共 29 条
[1]   Polymer-layered silicate nanocomposites: Preparation, properties and uses of a new class of materials [J].
Alexandre, Michael ;
Dubois, Philippe .
Materials Science and Engineering: R: Reports, 2000, 28 (1-2) :1-63
[2]  
DAVIS RD, 2001, POLYM PREPR, V42, P55
[3]   Structure determination of clay methyl methacrylate copolymer interlayer complexes by means of 13C solid state nmr [J].
Forte, C ;
Geppi, M ;
Giamberini, S ;
Ruggeri, G ;
Veracini, CA ;
Mendez, B .
POLYMER, 1998, 39 (12) :2651-2656
[4]   POLYVINYL ACETATE) DYNAMICS STUDIED BY PROTON AND C-13 NUCLEAR-MAGNETIC-RESONANCE IN THE SOLID-STATE [J].
GANAPATHY, S ;
CHACKO, VP ;
BRYANT, RG .
MACROMOLECULES, 1986, 19 (04) :1021-1029
[5]  
Giannelis EP, 1999, ADV POLYM SCI, V138, P107
[6]   Deuteron NMR study of polyaniline and polyaniline/clay nanocomposite [J].
Goddard, YA ;
Vold, RL ;
Hoatson, GL .
MACROMOLECULES, 2003, 36 (04) :1162-1169
[7]   NMR study of surfactant molecules intercalated in montmorillonite and in silylated montmorillonite [J].
Grandjean, J ;
Bujdák, J ;
Komadel, P .
CLAY MINERALS, 2003, 38 (03) :367-373
[8]  
GRANDJEAN J, 2002, ENCY SURFACE COLLOID, P3700
[9]  
GRANDJEAN J, 1998, ANNU REP NMR SPECTRO, V35, P216
[10]   Conformation of poly(ethylene oxide) intercalated in clay and MoS2 studied by two-dimensional double-quantum NMR [J].
Harris, DJ ;
Bonagamba, TJ ;
Schmidt-Rohr, K .
MACROMOLECULES, 1999, 32 (20) :6718-6724