Nickel-borate oxygen-evolving catalyst that functions under benign conditions

被引：673

作者：

Dinca, Mircea ^{[1
]}

Surendranath, Yogesh ^{[1
]}

Nocera, Daniel G. ^{[1
]}

机构：

[1] MIT, Dept Chem, Cambridge, MA 02139 USA

来源：

PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA | 2010年 / 107卷 / 23期

基金：

美国国家科学基金会;

关键词：

artificial photosynthesis; nonlegacy; personalized energy; water splitting; energy storage; COUPLED ELECTRON-TRANSFER; HYDROUS IRIDIUM OXIDE; THIN-FILMS; EVOLUTION REACTION; SOLAR-ENERGY; ANODIC DEPOSITION; WATER OXIDATION; CHARGE STORAGE; ELECTRODEPOSITION; ELECTROCHEMISTRY;

D O I：

10.1073/pnas.1001859107

中图分类号：

O [数理科学和化学]; P [天文学、地球科学]; Q [生物科学]; N [自然科学总论];

学科分类号：

07 ; 0710 ; 09 ;

摘要：

Thin catalyst films with electrocatalytic water oxidation properties similar to those of a recently reported Co-based catalyst can be electrodeposited from dilute Ni(2+) solutions in borate electrolyte at pH 9.2 (B(i)). The Ni-B(i) films can be prepared with precise thickness control and operate at modest overpotential providing an alternative to the Co catalyst for applications in solar energy conversion.

引用

页码：10337 / 10341

页数：5

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