The first X-ray crystal structure determination of a dinuclear complex trapped in the [low spin-high spin] state:: [FeII2(PMAT)2](BF4)4•DMF

被引：130

作者：

Klingele, MH

Moubaraki, B

Cashion, JD

Murray, KS

Brooker, S

机构：

[1] Univ Otago, Dept Chem, Dunedin, New Zealand

[2] Monash Univ, Sch Chem, Clayton, Vic 3800, Australia

[3] Monash Univ, Sch Phys & Mat Engn, Clayton, Vic 3800, Australia

来源：

CHEMICAL COMMUNICATIONS | 2005年 / 08期

关键词：

D O I：

10.1039/b415891a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The two metal centres in the doubly 1,2,4-triazole-bridged spin crossover complex [Fe-2(II)(PMAT)(2)](BF4)(4)center dot DMF (1 center dot DMF) are trapped in different spin states below ca. 200 K, with no evidence that this particular [LS-HS] species can be converted into the [LS-LS] form at ambient pressure.

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收藏

页码：987 / 989

页数：3

相关论文

共 31 条

[1] Cobalt(II) complexes of pyridazine or triazole containing ligands: spin-state control [J].

Beckmann, U ;

Brooker, S .

COORDINATION CHEMISTRY REVIEWS, 2003, 245 (1-2) :17-29

[2] Dicobalt(II) complexes of a triazolate-containing Schiff-base macrocycle: synthesis, structure and magnetism [J].

Beckmann, U ;

Brooker, S ;

Depree, CV ;

Ewing, JD ;

Moubaraki, B ;

Murray, KS .

DALTON TRANSACTIONS, 2003, (07) :1308-1313

[3] A dicobalt(II) complex of a triazolate-containing macrocycle reacts with nitromethane to yield an organometallic dicobalt(III) complex [J].

Beckmann, U ;

Ewing, JD ;

Brooker, S .

CHEMICAL COMMUNICATIONS, 2003, (14) :1690-1691

[4] Dinickel(II), dizinc(II) and dilead(II) complexes of a pyridazine-containing Schiff-base macrocycle [J].

Brandt, CD ;

Plieger, PG ;

Kelly, RJ ;

de Geest, DJ ;

Kennepohl, DK ;

Iremonger, SS ;

Brooker, S .

INORGANICA CHIMICA ACTA, 2004, 357 (14) :4265-4272

[5]

Brooker S, 2002, EUR J INORG CHEM, P2535

[6] Exchange-coupled high-spin, low-spin and spin-crossover dicobalt(II) complexes of a pyridazine-containing Schiff-base macrocycle: control of cobalt(II) spin state by choice of axial ligands [J].

Brooker, S ;

de Geest, DJ ;

Kelly, RJ ;

Plieger, PG ;

Moubaraki, B ;

Murray, KS ;

Jameson, GB .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 2002, (09) :2080-2087

[7] Complexes of thiophenolate-containing Schiff-base macrocycles and their amine analogues [J].

Brooker, S .

COORDINATION CHEMISTRY REVIEWS, 2001, 222 :33-56

[8]

Brooker S, 1999, ANGEW CHEM INT EDIT, V38, P408, DOI 10.1002/(SICI)1521-3773(19990201)38:3<408::AID-ANIE408>3.0.CO

[9]

2-P

[10]

DEGEEST DJ, UNPUB

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