Preparation of a novel β-CD-dimanganese complex with covalently bound photosensitizer

被引：9

作者：

Van Hoof, N

Keyes, TE

Forster, RJ

McNally, A

Russell, NR

机构：

[1] Dublin Inst Technol, Sch Chem, Dublin 8, Ireland

[2] Dublin City Univ, Sch Chem Sci, Dublin 9, Ireland

来源：

CHEMICAL COMMUNICATIONS | 2001年 / 13期

关键词：

D O I：

10.1039/b103363h

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The synthesis and structure of a novel donor-acceptor complex comprised of a photosensitising ruthenium polypyridyl moiety covalently linked to a beta -cyclodextrin unit bearing a hydroxy-bridged manganese(iii) dimer 1 is described; the dimanganese complex undergoes a photoinduced electron transfer and may represent an attractive model system for elucidating aspects of photosystem II.

引用

收藏

页码：1156 / 1157

页数：2

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