Poly(methylphenylsilylene)-block-polystyrene copolymer prepared by the use of a chloromethylphenyl end-capped poly(methylphenylsilylene) as a macromolecular initiator in an atom transfer radical polymerisation of styrene

被引：9

作者：

Lutsen, L

Cordina, GPG

Jones, RG ^{[1
]}

Schué, F

机构：

[1] Univ Kent, Sch Phys Sci, Ctr Mat Res, Canterbury CT2 7NR, Kent, England

[2] Univ Montpellier 2, Lab Macromol Chem, F-34095 Montpellier 5, France

来源：

EUROPEAN POLYMER JOURNAL | 1998年 / 34卷 / 12期

基金：

英国工程与自然科学研究理事会;

关键词：

D O I：

10.1016/S0014-3057(98)00041-X

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Block copolymers of poly(methylphenylsilylene) and poly(styrene) have been conveniently synthesised by using alpha,omega-di((chloromethyl)phenylethyl-dimethylsilyl)poly(methylphenylsilylene) as a macromolecular initiator for the bulk polymerisation of styrene in an atom transfer radical polymerisation reaction. Where appropriate, the structures of the precursor and the block copolymers have been confirmed using size exclusion chromatography and NMR spectroscopy. (C) 1998 Elsevier Science Ltd. All rights reserved.

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页码：1829 / 1837

页数：9

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