fac-tricarbonylchlorobis(pyridine-N)rhenium and fac-tricarbonylchlorobis(4,4′-bipyridine-N)rhenium

被引：26

作者：

Bélanger, S ^{[1
]}

Hupp, JT ^{[1
]}

Stern, CL ^{[1
]}

机构：

[1] Northwestern Univ, Dept Chem, Evanston, IL 60208 USA

来源：

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS | 1998年 / 54卷

关键词：

D O I：

10.1107/S0108270198006398

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Structural analyses for the title compounds, (OC-6-32)-tricarbonylchlorobis(pyridine-N)rhenium(I), [ReCl(C5H5N)(2)(CO)(3)], and (OC-6-32)-tricarbonylchlorobis-(4,4'-bipyridine-N)rhenium(I), [ReCl(C10H8N2)(2)(CO)(3)], show that both complexes have the expected fac-octahedral geometry. The bipyridine complex has local C-2 symmetry, with the rotation axis bisecting the N-Re-N' and OC-Re-CO angles. In contrast with closely related tetrameric assemblies which crystallize as porous channel-containing structures, the title compounds form dense crystals which are packed in a herring-bone fashion.

引用

页码：1596 / 1600

页数：5

共 22 条

[1] BELANGER S, 1998, UNPUB J AM CHEM SOC
[2] MONONUCLEAR AND BINUCLEAR PALLADIUM(II) RHENIUM(I) COMPLEXES CONTAINING A STERICALLY HINDERED TRINUCLEATING LIGAND - 2,3,8,9,14,15-HEXAMETHYL-5,6,11,12,17,18-HEXAAZATRINAPHTHALENE (HHTN)
CATALANO, VJ
LARSON, WE
OLMSTEAD, MM
GRAY, HB
[J]. INORGANIC CHEMISTRY, 1994, 33 (20) : 4502 - 4509
[3] SPECTROSCOPIC AND CRYSTALLOGRAPHIC CHARACTERIZATION OF (SIGMA-2-TERPYRIDYL)RE(CO)3CL - 2D-NMR EVIDENCE FOR A LINKAGE ISOMERIZATION REACTION
CIVITELLO, ER
DRAGOVICH, PS
KARPISHIN, TB
NOVICK, SG
BIERACH, G
OCONNELL, JF
WESTMORELAND, TD
[J]. INORGANIC CHEMISTRY, 1993, 32 (02) : 237 - 241
[4] FUJITA M, 1996, J CHEM SOC CHEM COMM, P1535
[5] GIORDANO PJ, 1979, J AM CHEM SOC, V101, P2888, DOI 10.1021/ja00505a016
[6] PHOTOCHEMICAL AND PHOTOPHYSICAL PROPERTIES OF FAC-[RE(CO)3(L)2CL] (L = QUINOLINE OR ISOQUINOLINE)
IHA, NM
FERRAUDI, G
[J]. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1994, (17): : 2565 - 2571
[7] JOHNSON CK, 1965, ORNL3794
[8] Reactions of dimesityldioxoosmium(VI) with bidentate N-heterocycles. Crystal structure of a dioxoosmium(VI) complex containing a molecular square
Leung, WH
Cheng, JYK
Hun, TSM
Che, CM
Wong, WT
Cheung, KK
[J]. ORGANOMETALLICS, 1996, 15 (05) : 1497 - 1501
[9] MEULENAER JD, 1965, ACTA CRYSTALLOGR, V19, P1014
[10] *MOL STRUCT CORP, 1995, TEXSAN SINGL CRYST S

← 1 2 3 →