Electron Capture by Polarizable Dipolar Targets: Numerical and Analytically Approximated Capture Probabilities

被引:26
作者
Dashevskaya, E. I. [1 ,2 ]
Litvin, I. [1 ,2 ]
Nikitin, E. E. [1 ,2 ]
Troe, J. [1 ,3 ]
机构
[1] Max Planck Inst Biophys Chem, D-37077 Gottingen, Germany
[2] Technion Israel Inst Technol, Schulich Fac Chem, IL-32000 Haifa, Israel
[3] Univ Gottingen, Inst Phys Chem, D-37077 Gottingen, Germany
关键词
STARK ENERGY-LEVELS; MOLECULES; ATTACHMENT; FIELD;
D O I
10.1021/jp110501n
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Numerically accurate and analytically approximated partial wave probabilities for the capture of a charged particle by a stationary polarizable dipole are presented over wide ranges of collision energies. The results facilitate the analysis of electron-molecule attachment in terms of capture rates, contributions from electron-phonon coupling, and kinetic properties when metastable anions are formed.
引用
收藏
页码:6825 / 6830
页数:6
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