First structurally characterized organometallic chloro oxo-peroxo compounds of molybdenum and tungsten

被引：34

作者：

Chakraborty, D ^{[1
]}

Bhattacharjee, M ^{[1
]}

Krätzner, R ^{[1
]}

Siefken, R ^{[1
]}

Roesky, HW ^{[1
]}

Usón, I ^{[1
]}

Schmidt, HG ^{[1
]}

机构：

[1] Univ Gottingen, Inst Anorgan Chem, D-37077 Gottingen, Germany

来源：

ORGANOMETALLICS | 1999年 / 18卷 / 01期

关键词：

D O I：

10.1021/om980732o

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Reactions of H2O2 with Cp*MoCl4 and Cp*WCl4 (Cp* = C5Me5) yield chloro oxo-peroxo complexes of the type Cp*MoO(O-2)Cl (1) and Cp*WO(O-2)Cl (2) in high yields. The compounds have been characterized using X-ray structural analysis.

引用

页码：106 / 108

页数：3

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