Reactivity of electrophilic μ-phosphinidene complexes with heterocumulenes:: formation of the first σ-π-aminophosphaimine complexes [Mn2(CO)8{μ-η1,η2-P(NiPr2) = NR}] and diazoalkane insertions into metal-phosphorus bonds

被引：22

作者：

Graham, TW

Udachin, KA

Carty, AJ

机构：

[1] Natl Res Council Canada, Steacie Inst Mol Sci, Ottawa, ON K1A 0R6, Canada

[2] Univ Ottawa, Ottawa Carleton Chem Inst, Ottawa, ON K1N 6N5, Canada

来源：

CHEMICAL COMMUNICATIONS | 2005年 / 35期

关键词：

D O I：

10.1039/b505472a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The bridging phosphinidene complexes [Mn-2(CO)(8)(mu- (PNPr2)-Pr-i)] and [Co-2(CO)(4)(mu-dppm)(mu-PNR2)] (NR2 = 5N(i)Pr(2), TMP) react with heterocumulenes RN3, CH2N2 and Ph2C=N=N to form complexes with mu-eta(1), eta(2)-aminophosphaimine, mu-eta(1), eta(2)-aminophosphaalkene phosphaalkene and mu-eta(1), eta(2)-aminophosphadiphenylmethylazaimine ligands, respectively.

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页码：4441 / 4443

页数：3

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