The effect of molecular shape and microphase segregation on the formation of liquid crystal phases in poly-ols

被引：12

作者：

West, JJ

Bonsergent, G

Mackenzie, G

Ewing, DF

Goodby, JW ^{[1
]}

Benvegnu, T

Plusquellec, D

Bachir, S

Bault, P

Douillet, O

Godé, P

Goethals, G

Martin, P

Villa, P

机构：

[1] Univ Hull, Sch Chem, Kingston Upon Hull HU6 7RX, N Humberside, England

[2] Ecole Natl Super Chim Rennes, CNRS, Lab Chim Organ & Subst Nat, F-35700 Rennes, France

[3] Univ Picardie, Fac Sci, Lab Chim Organ & Cinet, F-80039 Amiens, France

来源：

MOLECULAR CRYSTALS AND LIQUID CRYSTALS | 2001年 / 362卷

关键词：

D O I：

10.1080/10587250108025758

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

In this article we examine the effect of molecular shape on the formation of thermotropic phases of alkyl-substituted poly-ols. The relationship between the cross-sectional area of the hydrophilic head group with respect to the that of the hydrophilic tails determines the type of mesophase formed. The results obtained are similar to those found for the formation of lyotropic phases.

引用

页码：23 / 44

页数：22

共 20 条

[1]

Barrall E, 1979, ORG COAT PLAST CHEM, V40, P67

[2]

BONSERGENT G, 1997, UNPUB, V300, P341

[3] Molecular design of thermotropic liquid crystalline polyhydroxy amphiphiles exhibiting columnar and cubic mesophases of the normal type [J].