Rhodium(I) and iridium(I) phosphaferrocene complexes

被引：14

作者：

Sava, X ^{[1
]}

Mézailles, N ^{[1
]}

Ricard, L ^{[1
]}

Mathey, F ^{[1
]}

Le Floch, P ^{[1
]}

机构：

[1] Ecole Polytech, CNRS, UMR 7653, Lab Heteroelements & Coordinat, F-91128 Palaiseau, France

来源：

ORGANOMETALLICS | 1999年 / 18卷 / 04期

关键词：

D O I：

10.1021/om980838j

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The synthesis of 3,4-dimethylphosphaferrocene (1) complexes of rhodium ([Rh(1)(3)Cl] 2, and [Rh(1)(4)][BF4], 3) and iridium ([lr(1)(3)(COD)][BF4], 4) are reported. An X-ray crystal structure analysis of the homoleptic derivative 3 reveals that ligands arrange around the rhodium center without apparent steric congestion. Complex 4, which was also structurally characterized, adopts a trigonal bipyramid geometry in the solid state. The reaction. of 4 with H-2 under pressure yields the [Ir(1)(4)H-2](+) complex.

引用

页码：807 / 810

页数：4

共 32 条

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