Unconventional ring currents in an 'all-metal aromatic', Al42-

被引：101

作者：

Fowler, PW ^{[1
]}

Havenith, RWA ^{[1
]}

Steiner, E ^{[1
]}

机构：

[1] Univ Exeter, Sch Chem, Exeter EX4 4QD, Devon, England

来源：

CHEMICAL PHYSICS LETTERS | 2001年 / 342卷 / 1-2期

关键词：

D O I：

10.1016/S0009-2614(01)00559-0

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The square planar anion Al-4(2-) supports an unconventional diamagnetic ring current which originates in the a system, has negligible contribution from the two-electron pi system, and survives in pyramidal bimetallic clusters MAI, (M = Li, Na, Cu). (C) 2001 Elsevier Science B.V. All rights reserved.

引用

页码：85 / 90

页数：6

共 33 条

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