One-dimensional supramolecular assemblies based on a Re2(III,III) synthon and their solid-state phosphorescence

被引：15

作者：

Dequeant, MQ

McGuire, R

McMillin, DR ^{[1
]}

Ren, T

机构：

[1] Purdue Univ, Dept Chem, W Lafayette, IN 47907 USA

[2] Univ Miami, Dept Chem, Coral Gables, FL 33146 USA

来源：

INORGANIC CHEMISTRY | 2005年 / 44卷 / 19期

关键词：

D O I：

10.1021/ic051070f

中图分类号：

O61 [无机化学];

学科分类号：

070301 [无机化学]; 081704 [应用化学];

摘要：

Reactions between Re-2(DMBA)(4)(NO3)(2) (1; DMBA is dimethylbenzamidinate) and a bidentate dianion, either tungstate (WO42-) or terephthalte (1,4-(O2C)(2)C6H42-), resulted in the one-dimensional coordination polymers [Re-2(DMBA)(4)(mu-O,O'-WO4)](infinity) (2) and [Re-2(DMBA)(4)(mu-O,O'-WO4)(2)C6H4)](infinity) (3), respectively. Both polymers display phosphorescence from a (3)(delta -> delta(*)) state, which is significantly blue shifted from the phosphorescence previously observed for Re-2(DMBA)(4)Cl-2 type compounds.

引用

收藏

页码：6521 / 6523

页数：3

相关论文

共 43 条

[1]

Molecular squares with paramagnetic diruthenium corners: Synthetic and crystallographic challenges [J].

Angaridis, P ;

Berry, JF ;

Cotton, FA ;

Murillo, CA ;

Wang, XP .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2003, 125 (34) :10327-10334

[2]

Dicarboxylato-bridged diruthenium units in two different oxidation states:: the first step towards the synthesis of Creutz-Taube analogs with dinuclear Run+2 species [J].

Angaridis, P ;

Berry, JF ;

Cotton, FA ;

Lei, P ;

Lin, C ;

Murillo, CA ;

Villagrán, D .

INORGANIC CHEMISTRY COMMUNICATIONS, 2004, 7 (01) :9-13

[3]

STRUCTURE OF TETRA-N-BUTYRATODIRUTHENIUM CHLORIDE A COMPOUND WITH A STRONG METAL-METAL BOND [J].

BENNETT, MJ ;

CAULTON, KG ;

COTTON, FA .

INORGANIC CHEMISTRY, 1969, 8 (01) :1-&

[4]

Incorporating multiply bonded dirhenium species [Re2]n+ (n=4 or 5) into assemblies containing two or more such units [J].

Bera, JK ;

Angaridis, P ;

Cotton, FA ;

Petrukhina, MA ;

Fanwick, PE ;

Walton, RA .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2001, 123 (07) :1515-1516

[5]

Dinuclear complexes as connectors for carboxylates. Self-assembly of a molecular box [J].

Bonar-Law, RP ;

McGrath, TD ;

Singh, N ;

Bickley, JF ;

Steiner, A .

CHEMICAL COMMUNICATIONS, 1999, (24) :2457-2458

[6]

Direct observation of the luminescence from the 3δδ* excited state of Re2Cl2(p-OCH3form)4 [J].

Bradley, PM ;

Smith, LT ;

Eglin, JL ;

Turro, C .

INORGANIC CHEMISTRY, 2003, 42 (23) :7360-7362

[7]

Perfluoroterephthalate bridged complexes with M-M quadruple bonds:: (tBuCO2)3M2(μ-O2CC6F4CO2)M2(O2CtBu)3, where M = Mo or W. studies of solid-state, molecular, and electronic structure and correlations with electronic and Raman spectral data [J].

Bursten, BE ;

Chisholm, MH ;

Clark, RJH ;

Firth, S ;

Hadad, CM ;

Wilson, PJ ;

Woodward, PM ;

Zaleski, JM .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2002, 124 (41) :12244-12254

[8]

METAL METAL MULTIPLE BONDS IN ORDERED ASSEMBLIES .1. TETRANUCLEAR MOLYBDENUM AND TUNGSTEN CARBOXYLATES INVOLVING COVALENTLY LINKED M-M QUADRUPLE BONDS - MOLECULAR-MODELS FOR SUBUNITS OF ONE-DIMENSIONAL STIFF-CHAIN POLYMERS [J].

CAYTON, RH ;

CHISHOLM, MH ;

HUFFMAN, JC ;

LOBKOVSKY, EB .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1991, 113 (23) :8709-8724

[9]

Synthesis and characterization of Ru2(DMBA)4X2 (X = CN, N3, N(CN)2, I):: Controlling structural, redox, and magnetic properties with axial ligands [J].

Chen, WZ ;

Ren, T .

INORGANIC CHEMISTRY, 2003, 42 (26) :8847-8852

[10]

Electronic coupling between molybdenum or tungsten quadruple bonds linked by dicarboxylate ligands [J].

Chisholm, MH .

DALTON TRANSACTIONS, 2003, Royal Society of Chemistry (20) :3821-3828

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