A molecular approach to the intermediate band solar cell: The symmetric case

被引:81
作者
Ekins-Daukes, N. J. [1 ]
Schmidt, T. W. [2 ]
机构
[1] Univ London Imperial Coll Sci Technol & Med, Blackett Lab, London SW7 2AZ, England
[2] Univ Sydney, Sch Chem, Sydney, NSW 2006, Australia
关键词
D O I
10.1063/1.2970157
中图分类号
O59 [应用物理学];
学科分类号
摘要
Molecular materials may overcome some of the difficulties for making an intermediate band solar cell by storing energy in long-lived triplet states. Both the problems of fast nonradiative interband relaxation and selective photon absorption can be solved by this approach. A practical implementation of the molecular intermediate band solar cell is considered with a symmetric band alignment, resting on a proven triplet-triplet annihilation process. The limiting power conversion efficiency for this system exceeds that of a single bandgap device over a broad range, peaking at 40.6% for 1.9 eV under 1 sun illumination. (C) 2008 American Institute of Physics.
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页数:3
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共 17 条
[1]   PHOTOPHYSICAL PROPERTIES OF C60 [J].
ARBOGAST, JW ;
DARMANYAN, AP ;
FOOTE, CS ;
RUBIN, Y ;
DIEDERICH, FN ;
ALVAREZ, MM ;
ANZ, SJ ;
WHETTEN, RL .
JOURNAL OF PHYSICAL CHEMISTRY, 1991, 95 (01) :11-12
[2]  
*ASTM, 1999, G17303E1 ASTM, P83103
[3]   A general approach for non-coherently excited annihilation up-conversion: transforming the solar-spectrum [J].
Baluschev, S. ;
Yakutkin, V. ;
Miteva, T. ;
Wegner, G. ;
Roberts, T. ;
Nelles, G. ;
Yasuda, A. ;
Chernov, S. ;
Aleshchenkov, S. ;
Cheprakov, A. .
NEW JOURNAL OF PHYSICS, 2008, 10
[4]   Upconversion with ultrabroad excitation band: Simultaneous use of two sensitizers [J].
Baluschev, S. ;
Yakutkin, V. ;
Wegner, G. ;
Miteva, T. ;
Nelles, G. ;
Yasuda, A. ;
Chernov, S. ;
Aleshchenkov, S. ;
Cheprakov, A. .
APPLIED PHYSICS LETTERS, 2007, 90 (18)
[5]   Two pathways for photon upconversion in model organic compound systems [J].
Baluschev, S. ;
Yakutkin, V. ;
Wegner, G. ;
Minch, B. ;
Miteva, T. ;
Nelles, G. ;
Yasuda, A. .
JOURNAL OF APPLIED PHYSICS, 2007, 101 (02)
[6]   Limiting efficiency of an intermediate band solar cell under a terrestrial spectrum [J].
Bremner, Stephen P. ;
Levy, Michael Y. ;
Honsberg, Christiana B. .
APPLIED PHYSICS LETTERS, 2008, 92 (17)
[7]   Tandem dye-sensitized solar cell for improved power conversion efficiencies [J].
Dürr, M ;
Bamedi, A ;
Yasuda, A ;
Nelles, G .
APPLIED PHYSICS LETTERS, 2004, 84 (17) :3397-3399
[8]  
HERKSTROETER W, 1966, COMP MATER SCI, V88, P4769
[9]   Noncoherent low-power upconversion in solid polymer films [J].
Islangulov, Radiy R. ;
Lott, Joseph ;
Weder, Christoph ;
Castellano, Felix N. .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2007, 129 (42) :12652-+
[10]   Artificial photosynthesis based on dye-sensitized nanocrystalline TiO2 solar cells [J].
Lagref, J. -J. ;
Nazeeruddin, Md. K. ;
Graetzel, M. .
INORGANICA CHIMICA ACTA, 2008, 361 (03) :735-745