Synthesis of a symmetric cylindrical bis(crown ether) host and its complexation with paraquat

被引：73

作者：

Huang, FH

Zakharov, LN

Rheingold, AL

Ashraf-Khorassani, M

Gibson, HW ^{[1
]}

机构：

[1] Virginia Polytech Inst & State Univ, Dept Chem, Blacksburg, VA 24061 USA

[2] Univ Calif San Diego, Dept Chem & Biochem, La Jolla, CA 92093 USA

来源：

JOURNAL OF ORGANIC CHEMISTRY | 2005年 / 70卷 / 03期

关键词：

D O I：

10.1021/jo048111u

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The first cylindrical host for paraquat derivatives was prepared and characterized by X-ray analysis. Its complex with paraquat has 1:2 stoichiometry. The complexation is statistical and strong as shown by proton NMR characterization, electrospray mass spectrometry, and X-ray analysis.

引用

收藏

页码：809 / 813

页数：5

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