Peroxidase-catalyzed oxidative polymerization of 4,4′-dihydroxydiphenyl ether.: Formation of α,ω-hydroxyoligo(1,4-phenylene oxide) through an unusual reaction pathway

被引：32

作者：

Fukuoka, T

Tonami, H

Maruichi, N

Uyama, H

Kobayashi, S ^{[1
]}

Higashimura, H

机构：

[1] Kyoto Univ, Grad Sch Engn, Dept Chem Mat, Kyoto 6068501, Japan

[2] Japan Chem Innovat Inst, Joint Res Ctr Precis Polymerizat, NIMC, Tsukuba, Ibaraki 3058565, Japan

来源：

MACROMOLECULES | 2000年 / 33卷 / 24期

关键词：

D O I：

10.1021/ma001054w

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Peroxidase-catalyzed oxidative polymerization of 4,4′-dihydroxydiphenyl ether was demonstrated in an aqueous solution. This reaction led to the formation of α,ω-hydroxyoligo(1,4-phenylene oxide)s in moderate yields. Hydroquinone was also one of the products during the reaction. The corresponding data suggested that redistribution and/or rearrangement of the quinone-ketal intermediate took place to produce the oligomers and hydroquinone.

引用

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页码：9152 / 9155

页数：4

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