Enzymatic synthesis and nanostructural control of gallium oxide at low temperature

被引:121
作者
Kisailus, D
Choi, JH
Weaver, JC
Yang, WJ
Morse, DE [1 ]
机构
[1] Univ Calif Santa Barbara, Mat Res Lab, Santa Barbara, CA 93106 USA
[2] Univ Calif Santa Barbara, Inst Collaborat Biotechnol, Santa Barbara, CA 93106 USA
[3] Univ Calif Santa Barbara, Calif NanoSyst Inst, Santa Barbara, CA 93106 USA
[4] Univ Calif Santa Barbara, Dept Mol Cellular & Dev Biol, Inst Marine Sci, Santa Barbara, CA 93106 USA
关键词
D O I
10.1002/adma.200400815
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Nanostructural control of gallium oxide formation is achieved at low temperatures by the enzyme-catalyzed hydrolysis and polycondensation of gallium oxide precursors. Filaments of silicatein, a hydrolase originally discovered in a marine sponge, catalyze the hydrolysis of gallium(III) nitrate, producing oriented nanocrystallites along the length of the filaments (see Figure) in the absence of acid or alkali.
引用
收藏
页码:314 / +
页数:6
相关论文
共 30 条
[1]   Direct fabrication of large micropatterned single crystals [J].
Aizenberg, J ;
Muller, DA ;
Grazul, JL ;
Hamann, DR .
SCIENCE, 2003, 299 (5610) :1205-1208
[2]   First steps in harnessing the potential of biomineralization as a route to new high-performance composite materials [J].
Belcher, AM ;
Hansma, PK ;
Stucky, GD ;
Morse, DE .
ACTA MATERIALIA, 1998, 46 (03) :733-736
[3]   Biomimetic synthesis of ordered silica structures mediated by block copolypeptides [J].
Cha, JN ;
Stucky, GD ;
Morse, DE ;
Deming, TJ .
NATURE, 2000, 403 (6767) :289-292
[4]   Silicatein filaments and subunits from a marine sponge direct the polymerization of silica and silicones in vitro [J].
Cha, JN ;
Shimizu, K ;
Zhou, Y ;
Christiansen, SC ;
Chmelka, BF ;
Stucky, GD ;
Morse, DE .
PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA, 1999, 96 (02) :361-365
[5]  
Choi YC, 2000, ADV MATER, V12, P746, DOI 10.1002/(SICI)1521-4095(200005)12:10<746::AID-ADMA746>3.0.CO
[6]  
2-N
[7]   Higher-order organization by mesoscale self-assembly and transformation of hybrid nanostructures [J].
Cölfen, H ;
Mann, S .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2003, 42 (21) :2350-2365
[8]   Catalytic triads and their relatives [J].
Dodson, G ;
Wlodawer, A .
TRENDS IN BIOCHEMICAL SCIENCES, 1998, 23 (09) :347-352
[9]  
ERWIN G, 1952, ACTA CRYSTALLOGR, V5, P103
[10]   INNOVATIVE MATERIALS PROCESSING STRATEGIES - A BIOMIMETIC APPROACH [J].
HEUER, AH ;
FINK, DJ ;
LARAIA, VJ ;
ARIAS, JL ;
CALVERT, PD ;
KENDALL, K ;
MESSING, GL ;
BLACKWELL, J ;
RIEKE, PC ;
THOMPSON, DH ;
WHEELER, AP ;
VEIS, A ;
CAPLAN, AI .
SCIENCE, 1992, 255 (5048) :1098-1105