New star-shaped molecules with extended electronic delocalization

被引：26

作者：

Cherioux, F

Audebert, P

Hapiot, P

机构：

[1] Univ Franche Comte, Lab Chim & Electrochim Mol, F-25030 Besancon, France

[2] Univ Paris 07, Electrochim Mol Lab, CNRS, Unite Rech Associee 438, F-75251 Paris 05, France

来源：

CHEMISTRY OF MATERIALS | 1998年 / 10卷 / 07期

关键词：

D O I：

10.1021/cm9801441

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

New star-shaped molecules have been easily prepared with cyanuric chloride and some pyridine derivatives. These molecules present an important electronic delocalization between the attractive central ring and the three end donor groups. Molecular modeling by ab initio and PM3 semiempirical methods shows that the molecules belong to the D-3h group. These trications display one reduction wave for which the formal redox potentials have been determined.

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页码：1984 / 1989

页数：6

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