Electrochemical properties of some Sb or Te based alloys for candidate anode materials of lithium-ion batteries

被引：57

作者：

Zhao, XB ^{[1
]}

Cao, GS ^{[1
]}

Lv, CP ^{[1
]}

Zhang, LJ ^{[1
]}

Hu, SH ^{[1
]}

Zhu, TJ ^{[1
]}

Zhou, BC ^{[1
]}

机构：

[1] Zhejiang Univ, Dept Mat Sci & Engn, State Key Lab Silicon Mat, Hangzhou 310027, Peoples R China

来源：

JOURNAL OF ALLOYS AND COMPOUNDS | 2001年 / 315卷 / 1-2期

基金：

中国国家自然科学基金;

关键词：

electrode materials; electrochemical reactions; thermoelectric; ionic conduction;

D O I：

10.1016/S0925-8388(00)01311-6

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Some antimony or tellurium based thermoelectric alloys have been prepared and studied as new candidate anode materials for lithium-ion batteries. It was found that some thermoelectric antimonides yield a volume capacity for reversible lithium storage more than twice that of state elf the art carbon based materials. Ex-situ XRD analyses show that the semimetals such as antimony, bismuth and tellurium in the semiconducting thermoelectric alloys are the active elements for the lithium adsorption. However, inactive elements are also necessary for an alloy electrode to ensure the electrochemical capacity retention during cycling. (C) 2001 Elsevier Science B.V. All rights reserved.

引用

页码：265 / 269

页数：5

共 14 条

[1] Electrochemical reaction of lithium with the CoSb3 skutterudite [J].

Alcántara, R ;

Fernández-Madrigal, FJ ;

Lavela, P ;

Tirado, JL ;

Jumas, JC ;

Olivier-Fourcade, J .

JOURNAL OF MATERIALS CHEMISTRY, 1999, 9 (10) :2517-2521

[2] Will advanced lithium-alloy anodes have a chance in lithium-ion batteries? [J].

Besenhard, JO ;

Yang, J ;

Winter, M .

JOURNAL OF POWER SOURCES, 1997, 68 (01) :87-90

[3] On the aggregation of tin in SnO composite glasses caused by the reversible reaction with lithium [J].

Courtney, IA ;

McKinnon, WR ;

Dahn, JR .

JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1999, 146 (01) :59-68

[4] Key factors controlling the reversibility of the reaction of lithium with SnO2 and Sn2BPO6 glass [J].

Courtney, IA ;

Dahn, JR .

JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1997, 144 (09) :2943-2948

[5] CHEMICAL BONDING IN BISMUTH TELLURIDE [J].

DRABBLE, JR ;

GOODMAN, CHL .

JOURNAL OF PHYSICS AND CHEMISTRY OF SOLIDS, 1958, 5 (1-2) :142-144

[6] Tin-based amorphous oxide: A high-capacity lithium-ion-storage material [J].

Idota, Y ;

Kubota, T ;

Matsufuji, A ;

Maekawa, Y ;

Miyasaka, T .

SCIENCE, 1997, 276 (5317) :1395-1397

[7] Thermoelectric properties of the skutterudite Co1-xFexSb3 system [J].

Katsuyama, S ;

Shichijo, Y ;

Ito, M ;

Majima, K ;

Nagai, H .

JOURNAL OF APPLIED PHYSICS, 1998, 84 (12) :6708-6712

[8] First-principles study of Zn-Sb thermoelectrics [J].

Kim, SG ;

Mazin, II ;

Singh, DJ .

PHYSICAL REVIEW B, 1998, 57 (11) :6199-6203

[9] Mechanically alloyed Sn-Fe(-C) powders as anode materials for Li-ion batteries -: III.: Sn2Fe:SnFe3C active/inactive composites [J].

Mao, O ;

Dahn, JR .

JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1999, 146 (02) :423-427

[10]

Mao O, 1999, J ELECTROCHEM SOC, V146, P405, DOI 10.1149/1.1391622

← 1 2 →