One-Pot Synthesis of Cu1.94S-CdS and Cu1.94S-ZnxCd1-xS Nanodisk Heterostructures

被引：101

作者：

Regulacio, Michelle D. ^{[2
]}

Ye, Chen ^{[1
,2
]}

Lim, Suo Hon ^{[2
]}

Bosman, Michel ^{[2
]}

Polavarapu, Lakshminarayana ^{[1
]}

Koh, Wei Ling ^{[2
]}

Zhang, Jie ^{[2
]}

Xu, Qing-Hua ^{[1
]}

Han, Ming-Yong ^{[2
,3
]}

机构：

[1] Natl Univ Singapore, Dept Chem, Singapore 117543, Singapore

[2] Agcy Sci Technol & Res, Inst Mat Res & Engn, Singapore 117602, Singapore

[3] Natl Univ Singapore, Div Bioengn, Singapore 117576, Singapore

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2011年 / 133卷 / 07期

关键词：

COPPER SULFIDE; CONVERSION EFFICIENCY; CDS-CU2S CELLS; NANOCRYSTALS; DESIGN; FABRICATION; NANORODS;

D O I：

10.1021/ja1090589

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Nanodisk heterostructures consisting of monoclinic Cu1.94S and wurtzite CdS have been colloidally synthesized for the first time. Initially, hexagonal-shaped nanodisks of Cu1.94S were produced upon thermolysis of a copper complex in a solvent mixture of HDA and TOA at 250 degrees C. Rapid addition of Cd precursor to the reaction mixture resulted in the partial conversion of Cu1.94S into CdS, yielding Cu1.94S-CdS nanoheterostructures. The original morphology of the Cu1.94S nanodisks was conserved during the transformation. When Zn precursor was added together with the Cd precursor, Cu1.94S-ZnxCd1-xS nanodisks were generated. These two-component nanostructures are potentially useful in the fabrication of heterojunction solar cells.

引用

页码：2052 / 2055

页数：4

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