Synthesis and extraction behaviour of calix[4]arenes partially substituted at the wide rim by carbamoylmethylphosphine oxide (CMPO) functions

被引：22

作者：

Arnaud-Neu, F ^{[1
]}

Barboso, S

Böhmer, V

Brisach, F

Delmau, L

Dozol, JF

Mogck, O

Paulus, EF

Saadioui, M

Shivanyuk, A

机构：

[1] ULP, CNRS, UMR 7512, Ecole Europeenne Chim Polymeres Mat,Lab Chim Phys, F-67087 Strasbourg, France

[2] Univ Mainz, Fachbereich Chem & Pharm, D-55099 Mainz, Germany

[3] CEA Cadarache, DES, SEO, LPTE, F-13108 St Paul Les Durance, France

[4] Univ Frankfurt, Inst Mineral Kristallog, D-60325 Frankfurt, Germany

来源：

AUSTRALIAN JOURNAL OF CHEMISTRY | 2003年 / 56卷 / 11期

关键词：

D O I：

10.1071/CH03163

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Tetraethers of calix[4]arenes fixed in the cone conformation and substituted at their wide rim by one to three CMPO residues and hydrogen atoms or t-butyl moieties in the remaining position(s) were synthesized. Liquid/liquid extraction studies of selected lanthanides and actinides were undertaken with these calix[4]arenes, including also a linear trimer, in order to obtain a better understanding for the extraction properties of the corresponding calix[4]arene substituted by four CMPO functions. The structure of the 1,3-di-CMPO derivative was confirmed by single crystal X-ray analysis.

引用

页码：1113 / 1119

页数：7

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