Fluorodesilylation of alkenyltrimethylsilanes: a new route to fluoroalkenes and difluoromethyl-substituted amides, alcohols or ethers

被引：54

作者：

Greedy, B ^{[1
]}

Gouverneur, V ^{[1
]}

机构：

[1] Univ Oxford, Dyson Perrins Lab, Oxford OX1 3QY, England

来源：

CHEMICAL COMMUNICATIONS | 2001年 / 03期

关键词：

D O I：

10.1039/b009179k

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A range of alkenyltrimethylsilanes are converted to alkenyl fluorides by reaction with one equivalent of Selectfluor(TM) (1-chloromethyl-4-fluoro-1,4-diazoniabicyclo[2.2.2]octane bis(tetrafluoroborate)), or difluoromethyl-substituted alcohols, ethers or amides using an excess of Selectfluor(TM) in the presence of various nucleophiles.

引用

页码：233 / 234

页数：2

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