Plasma-Enhanced Catalytic CuO Nanowires for CO Oxidation

被引:137
作者
Feng, Yunzhe [2 ]
Zheng, Xiaolin [1 ]
机构
[1] Stanford Univ, Dept Mech Engn, Stanford, CA 94305 USA
[2] Stanford Univ, Dept Mat Sci & Engn, Stanford, CA 94305 USA
关键词
Catalytic CO oxidation; CuO nanowires; plasma enhancement; Cu oxidation states; SURFACE;
D O I
10.1021/nl1034545
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
We report the first experimental study of catalytic CO oxidation over copper oxide (CuO) nanowires (NWs) grown directly on copper meshes. The catalytic activity of CuO NWs is significantly improved by a brief argon or hydrogen radio frequency plasma treatment. The plasma enhancement effect comes from the generation of grain boundaries and the reduction of Cu(II) to the more active oxidation state Cu(I) according to our TEM. XPS, and kinetic study.
引用
收藏
页码:4762 / 4766
页数:5
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共 25 条
  • [1] FTIR study of carbon monoxide oxidation and scrambling at room temperature over copper supported on ZnO and TiO2 .1.
    Boccuzzi, F
    Chiorino, A
    [J]. JOURNAL OF PHYSICAL CHEMISTRY, 1996, 100 (09) : 3617 - 3624
  • [2] Surface and catalytic properties of the CuO/Al2O3 system as influenced by doping with CeO2 or ZrO2 and by γ-irradiation
    El-Shobaky, GA
    Radwan, FM
    Turky, AEM
    El-Moemen, AA
    [J]. ADSORPTION SCIENCE & TECHNOLOGY, 2001, 19 (10) : 779 - 793
  • [3] Methane oxidation over catalytic copper oxides nanowires
    Feng, Yunzhe
    Rao, Pratap M.
    Kim, Dong Rip
    Zheng, Xiaolin
    [J]. PROCEEDINGS OF THE COMBUSTION INSTITUTE, 2011, 33 : 3169 - 3175
  • [4] Single-Step Process To Prepare CeO2 Nanotubes with Improved Catalytic Activity
    Gonzalez-Rovira, Leandro
    Sanchez-Amaya, Jose M.
    Lopez-Haro, Miguel
    del Rio, Eloy
    Hungria, Ana B.
    Midgley, Paul
    Calvino, Jose J.
    Bernal, Serafin
    Botana, F. Javier
    [J]. NANO LETTERS, 2009, 9 (04) : 1395 - 1400
  • [5] Synthesis and characterization of CuO/TiO2 catalysts for low-temperature CO oxidation
    Huang, Jing
    Wang, Shurong
    Zhao, Yingqiang
    Wang, Xiaoying
    Wang, Shuping
    Wu, Shihua
    Zhang, Shoumin
    Huang, Weiping
    [J]. CATALYSIS COMMUNICATIONS, 2006, 7 (12) : 1029 - 1034
  • [6] CO oxidation behavior of copper and copper oxides
    Huang, TJ
    Tsai, DH
    [J]. CATALYSIS LETTERS, 2003, 87 (3-4) : 173 - 178
  • [7] CARBON-MONOXIDE OXIDATION OVER 3 DIFFERENT OXIDATION-STATES OF COPPER - METALLIC COPPER, COPPER (I) OXIDE, AND COPPER (II) OXIDE - A SURFACE SCIENCE AND KINETIC-STUDY
    JERNIGAN, GG
    SOMORJAI, GA
    [J]. JOURNAL OF CATALYSIS, 1994, 147 (02) : 567 - 577
  • [8] CuO nanowires can be synthesized by heating copper substrates in air
    Jiang, XC
    Herricks, T
    Xia, YN
    [J]. NANO LETTERS, 2002, 2 (12) : 1333 - 1338
  • [9] Reactivity of the Cu2O(100) surface: Insights from first principles calculations
    Le, Duy
    Stolbov, Sergey
    Rahman, Talat S.
    [J]. SURFACE SCIENCE, 2009, 603 (10-12) : 1637 - 1645
  • [10] Transition metal-promoted oxidation catalysis by fluorite oxides: A study of CO oxidation over Cu-CeO2
    Liu, W
    Flytzani-Stephanopoulos, M
    [J]. CHEMICAL ENGINEERING JOURNAL, 1996, 64 (02): : 283 - 294