Synthesis and Characterization of Polyaniline/MCM-41 Nanocomposites and Their Photocatalytic Activity

被引:11
作者
Ameen, Sadia [1 ]
Im, Yu-Bin [1 ]
Jo, Chul Gi [1 ]
Kim, Young Soon [1 ]
Shin, Hyung-Shik [1 ]
机构
[1] Chonbuk Natl Univ, Energy Mat & Surface Sci Lab, Solar Energy Res Ctr, Sch Chem Engn, Jeonju 561756, South Korea
关键词
Mesoporous Material; Polyaniline; Organic-Inorganic Nanocomposite; Methylene Blue; Dye Degradation; MESOPOROUS MOLECULAR-SIEVES; POLYMERIZATION; DEGRADATION; WATER; DYES;
D O I
10.1166/jnn.2011.3161
中图分类号
O6 [化学];
学科分类号
070301 [无机化学];
摘要
The novel organic-inorganic nanocomposites were synthesized via in-situ polymerization of polyaniline (PANI) with mesoporous silica (MCM-41) for methylene blue (MB) dye degradation under visible light. The synthesized PANI/MCM-41 nanocomposites were characterized through Fourier transform infrared (FTIR), X-ray diffraction (XRD), Raman spectroscopy, field emission scanning electron microscopy (FESEM), and UV-visible studies. The structural and optical properties confirmed the interaction between PANI and MCM-41. The photocatalytic experiments showed that the MB dye was efficiently degraded by similar to 70% under light irradiation over the surface of the PANI/MCM-41 nanocomposites. The degradation might occur due to the efficient charge separation of the e(-)-h(+) pairs at the interface of PANI and MCM-41 in the excited state under light irradiation.
引用
收藏
页码:541 / 545
页数:5
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