Self-assembly of an interlaced triple-stranded molecular braid with an unprecedented topology through hydrogen-bonding interactions

被引：193

作者：

Luan, XJ

Wang, YY ^{[1
]}

Li, DS

Liu, P

Hu, HM

Shi, QZ

Peng, SM

机构：

[1] Northwest Univ, Shaanxi Key Lab Physicoinorgan Chem, Dept Chem, Xian 710069, Shaanxi, Peoples R China

[2] Natl Taiwan Univ, Dept Chem, Taipei 10764, Taiwan

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2005年 / 44卷 / 25期

关键词：

coordination polymers; copper; self-assembly; supramolecular chemistry; topology;

D O I：

10.1002/anie.200500744

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(Figure Presented) Molecular weaving: Mixing a CuII complex having a paddle-wheel structure with a highly flexible neutral 1,3-bis(4-pyridyl)-propane ligand (1:2 ratio) gives an interlaced braid which looks just like a hair plait (see X-ray crystallographic structure). The three strands are held together through hydrogen-bonding interactions. © 2005 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：3864 / 3867

页数：4

共 67 条

[1]

Batten S.R., 1998, ANGEW CHEM, V110, P1558, DOI DOI 10.1002/(SICI)1521-3757(19980605)110:11<1558::AID-ANGE1558>3.0.CO

[2]

2-7

[3] An alternative to interpenetration whereby nets with large windows may achieve satisfactory space filling [J].