Tuning of luminescence spectra of neutral ruthenium(II) complexes by crystal waters

被引：32

作者：

Abe, T ^{[1
]}

Shinozaki, K ^{[1
]}

机构：

[1] Yokohama City Univ, Grad Sch Integrated Sci, Dept Chem, Yokohama, Kanagawa 2360027, Japan

来源：

INORGANIC CHEMISTRY | 2005年 / 44卷 / 04期

关键词：

D O I：

10.1021/ic049169u

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Neutral ruthenium(II) complexes [RuLL'(CN)(2)] (L, L' = bpy, dmb, dbb; bpy = 2,2'-bipyridine, dmb = 4,4'-dimethyl-2,2'-bipyridine, dbb = 4,4'-tert-butyl-2,2'-bipyridine) were prepared, and the luminescence characteristics of the complexes in the solid state were measured. The luminescence was tuned by crystal waters included in the crystals; for example, [Ru(dbb)(2)(CN)(2)].2H(2)O, [Ru(dbb)(2)(CN)(2)]-H2O, and [Ru(dbb)(2)(CN)(2)] emit luminescence at 640, 685, and 740 nm, respectively.

引用

页码：849 / 851

页数：3

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