Synthesis and characterization of iron(III) phosphonate cage complexes

被引：155

作者：

Tolis, EI ^{[1
]}

Helliwell, M ^{[1
]}

Langley, S ^{[1
]}

Raftery, J ^{[1
]}

Winpenny, REP ^{[1
]}

机构：

[1] Univ Manchester, Dept Chem, Manchester M13 9PL, Lancs, England

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2003年 / 42卷 / 32期

关键词：

cage compounds; iron; phosphonates; supramolecular chemistry;

D O I：

10.1002/anie.200351764

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Sophisticated architectures can be built from oxo-centered carboxylate triangles linked together by phosphonates. This suggests that the phosphonate ligands could function as a means for building larger entities from carboxylate cages. The incorporation of a peroxide unit into the cage structures is also feasible, for example in the hexanuclear cage depicted.

引用

页码：3804 / 3808

页数：5

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