Bis[tris(1,3-diaminopropane)manganese(II)]octasulfidotetraantimonate(III) dihydrate

被引：12

作者：

Engelke, L ^{[1
]}

Bensch, W ^{[1
]}

机构：

[1] Univ Kiel, Inst Anorgan Chem, D-24098 Kiel, Germany

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2003年 / 59卷

关键词：

D O I：

10.1107/S1600536803011036

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

Yellow crystals of [Mn(pn)(3)](2)[Sb4S8].2H(2)O (pn=1,2-diaminopropane) were synthesized under solvothermal conditions by reacting elemental Mn, Sb and S in an aqueous solution of 1,2-diaminopropane. The structure is composed of cyclic [Sb4S8](4-). anions and octahedral [Mn(pn)(3)](2+) cations, both stacked in a rod-like manner along the a axis. The anion sits on a centre of symmetry. Between the anions and the cations there is an extended hydrogen-bonding network.

引用

页码：M378 / M380

页数：3

共 17 条

[1] Solvothermal synthesis of [Ni(C4H13N3)2]2Sb4S8:: the first compound with a cyclic [Sb4S8]4- anion [J].