Analysis of pesticides and their degradation products in rainwater: A probe into their atmospheric degradation

被引：14

作者：

Jager, ME ^{[1
]}

Bourbon, C ^{[1
]}

Levsen, K ^{[1
]}

机构：

[1] Fraunhofer Inst Toxicol & Aerosol Res, D-30625 Hannover, Germany

来源：

INTERNATIONAL JOURNAL OF ENVIRONMENTAL ANALYTICAL CHEMISTRY | 1998年 / 70卷 / 1-4期

关键词：

pesticides; degradation products; rain; precipitation; triazines; atmosphere;

D O I：

10.1080/03067319808032611

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

Rainwater samples collected in Hannover (Germany) in 1996 were analyzed for twelve pesticides. gamma-HCH, metolachlor, atrazine and terbuthylazine were determined in average concentrations ranging from 19 - 63 ng/L during the application period. In addition, three degradation products of atrazine, i.e. desethylatrazine, desisopropylatrazine and desethyldesisopropylatrazine, and one degradation product of terbuthylazine, i.e. desethylterbuthylazine, were found in concentrations which were equal or even surpassed those of the parent compounds. The analysis of degradation products in rainwater represents a probe into the degradation of pesticides in the atmosphere.

引用

页码：149 / 162

页数：14

共 49 条

[1]

ATKINSON R, 1992, BRIGHTON CROP PROTECTION CONFERENCE : PESTS AND DISEASES - 1992, VOLS 1-3, P469

[2] SIMULTANEOUS DETERMINATION OF TRIAZINES INCLUDING ATRAZINE AND THEIR MAJOR METABOLITES HYDROXYATRAZINE, DESETHYLATRAZINE, AND DEISOPROPYLATRAZINE IN NATURAL-WATERS [J].

BERG, M ;

MULLER, SR ;

SCHWARZENBACH, RP .

ANALYTICAL CHEMISTRY, 1995, 67 (11) :1860-1865

[3] Evaluating the environmental fate of atrazine in France [J].

Bintein, S ;

Devillers, J .

CHEMOSPHERE, 1996, 32 (12) :2441-2456

[4]

*BIOL BUND LAND FO, 1995, ABT PFLANZ ANW

[5] INVESTIGATIONS OF THE EVAPORATION OF SELECTED PESTICIDES FROM NATURAL AND MODEL SURFACES IN FIELD AND LABORATORY [J].

BOEHNCKE, A ;

SIEBERS, J ;

NOLTING, HG .

CHEMOSPHERE, 1990, 21 (09) :1109-1124

[6] OCCURRENCE OF TRIAZINES IN THE ATMOSPHERIC FALLOUT ON THE CATCHMENT BASIN OF THE RIVER MARNE (FRANCE) [J].

CHEVREUIL, M ;

GARMOUMA, M .

CHEMOSPHERE, 1993, 27 (09) :1605-1608

[7] COMPARATIVE PHOTODEGRADATION RATES OF ALACHLOR AND BENTAZONE IN NATURAL-WATER AND DETERMINATION OF BREAKDOWN PRODUCTS [J].

CHIRON, S ;

ABIAN, J ;

FERRER, M ;

SANCHEZBAEZA, F ;

MESSEGUER, A ;

BARCELO, D .

ENVIRONMENTAL TOXICOLOGY AND CHEMISTRY, 1995, 14 (08) :1287-1298

[8] DISSIPATION OF PESTICIDES FROM SOIL BY VOLATILIZATION OF DEGRADATION PRODUCTS .1. LINDANE AND DDT [J].

CLIATH, MM ;

SPENCER, WF .

ENVIRONMENTAL SCIENCE & TECHNOLOGY, 1972, 6 (10) :910-&

[9]

GEISSLER A, 1993, VOM WASSER, V80, P357

[10] ENZYME-IMMUNOASSAY BASED SURVEY OF PRECIPITATION AND SURFACE-WATER FOR THE PRESENCE OF ATRAZINE, METOLACHLOR AND 2,4-D [J].

HALL, JC ;

VANDEYNZE, TD ;

STRUGER, J ;

CHAN, CH .

JOURNAL OF ENVIRONMENTAL SCIENCE AND HEALTH PART B-PESTICIDES FOOD CONTAMINANTS AND AGRICULTURAL WASTES, 1993, 28 (05) :577-598

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