Organic-inorganic cooperative molecular recognition in nanostructure of alkyl-grafted MCM-41

被引:33
作者
Inumaru, K [1 ]
Inoue, Y [1 ]
Kakii, S [1 ]
Nakano, T [1 ]
Yamanaka, S [1 ]
机构
[1] Hiroshima Univ, Grad Sch Engn, Dept Appl Chem, Higashihiroshima 7398527, Japan
关键词
D O I
10.1246/cl.2003.1110
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Molecules having hydrophobic and hydrophilic groups such as 4-n-heptylaniline and 4-nonylphenol, an endocrine disrupter, fit the organic-inorganic nanostructure in alkyl-grafted MCM-41, interacting with the inorganic walls as well as the organic moiety, and thus the adsorbent achieves high molecular adsorption selectivity.
引用
收藏
页码:1110 / 1111
页数:2
相关论文
共 20 条
[1]   SOMC@PMS. Surface organometallic chemistry at periodic mesoporous silica [J].
Anwander, R .
CHEMISTRY OF MATERIALS, 2001, 13 (12) :4419-4438
[2]   Chiral copper(II) bisoxazoline covalently anchored to silica and mesoporous MCM-41 as a heterogeneous catalyst for the enantioselective Friedel-Crafts hydroxyalkylation [J].
Corma, A ;
García, H ;
Moussaif, A ;
Sabater, MJ ;
Zniber, R ;
Redouane, A .
CHEMICAL COMMUNICATIONS, 2002, (10) :1058-1059
[3]   Solubilization in confined surfactant mesophases [J].
Denoyel, R ;
Rey, ES .
LANGMUIR, 1998, 14 (25) :7321-7323
[4]   Functionalized monolayers on ordered mesoporous supports [J].
Feng, X ;
Fryxell, GE ;
Wang, LQ ;
Kim, AY ;
Liu, J ;
Kemner, KM .
SCIENCE, 1997, 276 (5314) :923-926
[5]   Sorption of hydrophobic molecules by organic/inorganic mesostructures [J].
Hanna, K ;
Beurroies, I ;
Denoyel, R ;
Desplantier-Giscard, D ;
Galarneau, A ;
Di Renzo, F .
JOURNAL OF COLLOID AND INTERFACE SCIENCE, 2002, 252 (02) :276-283
[6]   Syntheses of highly ordered mesoporous materials, FSM-16, derived from kanemite [J].
Inagaki, S ;
Koiwai, A ;
Suzuki, N ;
Fukushima, Y ;
Kuroda, K .
BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1996, 69 (05) :1449-1457
[7]   SYNTHESIS OF HIGHLY ORDERED MESOPOROUS MATERIALS FROM A LAYERED POLYSILICATE [J].
INAGAKI, S ;
FUKUSHIMA, Y ;
KURODA, K .
JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1993, (08) :680-682
[8]   Molecular selective adsorption of nonylphenol in aqueous solution by organo-functionalized mesoporous silica [J].
Inumaru, K ;
Kiyoto, J ;
Yamanaka, S .
CHEMICAL COMMUNICATIONS, 2000, (11) :903-904
[9]   Organic-functionalized molecular sieves as shape-selective catalysts [J].
Jones, CW ;
Tsuji, K ;
Davis, ME .
NATURE, 1998, 393 (6680) :52-54
[10]   Molecular imprinting of bulk, microporous silica [J].
Katz, A ;
Davis, ME .
NATURE, 2000, 403 (6767) :286-289