Synthesis, structure and second harmonic generation of novel inorganic-organic hybrid, (p-cyano-1-hydrogenpyridinium)2CdI4

被引：17

作者：

Ren, P

Qin, JG ^{[1
]}

Liu, T

Zhang, SW

机构：

[1] Wuhan Univ, Dept Chem, Wuhan 430072, Peoples R China

[2] Peking Univ, State Key Lab Struct Chem Stable & Unstable Speci, Coll Chem & Mol Engn, Beijing 100871, Peoples R China

来源：

INORGANIC CHEMISTRY COMMUNICATIONS | 2004年 / 7卷 / 01期

关键词：

hybrid; synthesis; structure; second harmonic generation;

D O I：

10.1016/j.inoche.2003.10.031

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A novel noncentrosymmetric inorganic-organic hybrid compound, (CHP)(2)CdI4 (CHP = 4-cyano-1-hydrogen pyridinium), has been synthesized and the structure contains randomly arrayed CHP cations with two possible orientations, which is stabilized via hydrogen-bonding interactions with isolated and perfectly packed CdI42- tetrahedrons, showing a moderate second harmonic generation (SHG) of about three times as large as that of KDP. (C) 2003 Published by Elsevier B.V.

引用

页码：134 / 136

页数：3

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