Advances in structurally characterized lanthanide alkoxide, aryloxide, and silyloxide compounds

被引：109

作者：

Boyle, Timothy J. ^{[1
]}

Ottley, Leigh Anna M. ^{[1
]}

机构：

[1] Adv Mat Lab, Sandia Natl Labs, Albuquerque, NM 87106 USA

来源：

CHEMICAL REVIEWS | 2008年 / 108卷 / 06期

关键词：

D O I：

10.1021/cr0401063

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

An overview regarding the progress made in structurally characterized lanthanide alkoxides is given. There were two issues that has been reviewed as with the large cation size combined with d and f orbitals and the steric bulk of the uninegative alkoxide ligands. A focus has been given on the structurally characterized Ln(OR)x that has been organized in terms of ligand steric bulk and by metal. In addition, a large number of homoleptic alkoxide compounds have also been structurally characterized. Other topics that have been discussed include the aliphatic alkoxides, aryloxides, mixed alkoxide derivatives, and the siloxides derivatives.

引用

页码：1896 / 1917

页数：22

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