Rhodium(II) catalyzed intramolecular insertion of carbenoids derived from 2-pyrrolyl and 3-indolyl α-diazo-β-ketoesters and α-diazoketones

被引：26

作者：

Cuevas-Yañez, E

Muchowski, JM

Cruz-Almanza, R

机构：

[1] Univ Nacl Autonoma Mexico, Inst Quim, Mexico City 04510, DF, Mexico

[2] Roche Palo Alto, Dept Chem, Palo Alto, CA 94304 USA

来源：

TETRAHEDRON | 2004年 / 60卷 / 07期

关键词：

rhodium carbenoids; alpha-diazo-beta-ketoesters; alpha-diazoketones; insertion pyrrol; indol;

D O I：

10.1016/j.tet.2003.12.019

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

alpha-Diazo-beta-ketoesters and alpha-diazoketones derived from 2-pyrrolylacetic, 2-pyrrolylpropionic, 3-indolylacetic and 3-indolylpropionic acids afforded carbenoid derived cyclization products on treatment with catalytic rhodium(II) acetate. (C) 2003 Elsevier Ltd. All rights reserved.

引用

收藏

页码：1505 / 1511

页数：7

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