Cycle and rate properties of mesoporous tin anode for lithium ion secondary batteries

被引:35
作者
Nara, Hiroki [1 ]
Fukuhara, Yoshiki [1 ]
Takai, Azusa [1 ]
Komatsu, Masaki [1 ]
Mukaibo, Hitomi [1 ]
Yamauchi, Yusuke [2 ]
Momma, Toshiyuki [3 ,4 ]
Kuroda, Kazuyuki [1 ,4 ]
Osaka, Tetsuya [1 ]
机构
[1] Waseda Univ, Grad Sch Sci & Engn, Shinjuku Ku, Tokyo 1698555, Japan
[2] Natl Inst Mat Sci, WPI Res Ctr, Int Ctr Mat Nanoarchitecton MANA, Tsukuba, Ibaraki 3050044, Japan
[3] Waseda Univ, Waseda Inst Adv Study, Tokyo 1698050, Japan
[4] Japan Sci & Technol Agcy, CREST, Kawaguchi, Saitama 3320012, Japan
关键词
D O I
10.1246/cl.2008.142
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A mesoporous Sn anode was electrodeposited in the presence of lyotropic liquid crystals made of nonionic surfactants. The introduction of mesoporous structure was effective for the accommodation of volume change of Sn during charge and discharge cycling of Li ions. The discharge capacity of the mesoporous Sn anode at 1 C rate was as high as 425 mA h g(-1) at the 100th cycle, and that was as high as 320 mA It g(-1) at the 100th cycle even though at 5 degrees C rate.
引用
收藏
页码:142 / 143
页数:2
相关论文
共 14 条
[1]  
Attard GS, 2000, MACROMOL SYMP, V156, P179, DOI 10.1002/1521-3900(200007)156:1<179::AID-MASY179>3.0.CO
[2]  
2-7
[3]   Liquid-crystal templates for nanostructured metals [J].
Attard, GS ;
Goltner, CG ;
Corker, JM ;
Henke, S ;
Templer, RH .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1997, 36 (12) :1315-1317
[4]   Electrochemical and in situ x-ray diffraction studies of the reaction of lithium with tin oxide composites [J].
Courtney, IA ;
Dahn, JR .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1997, 144 (06) :2045-2052
[5]   Tin-based amorphous oxide: A high-capacity lithium-ion-storage material [J].
Idota, Y ;
Kubota, T ;
Matsufuji, A ;
Maekawa, Y ;
Miyasaka, T .
SCIENCE, 1997, 276 (5317) :1395-1397
[6]  
Inoue H., 2006, INT M LITH BATT IMLB
[7]   Amorphous tin oxide films: preparation and characterization as an anode active material for lithium ion batteries [J].
Mohamedi, M ;
Lee, SJ ;
Takahashi, D ;
Nishizawa, M ;
Itoh, T ;
Uchida, I .
ELECTROCHIMICA ACTA, 2001, 46 (08) :1161-1168
[8]   Changes of electro-deposited Sn-Ni alloy thin film for lithium ion battery anodes during charge discharge cycling [J].
Mukaibo, H ;
Momma, T ;
Osaka, T .
JOURNAL OF POWER SOURCES, 2005, 146 (1-2) :457-463
[9]   Electrodeposited Sn-Ni alloy film as a high capacity anode material for lithium-ion secondary batteries [J].
Mukaibo, H ;
Sumi, T ;
Yokoshima, T ;
Momma, T ;
Osaka, T .
ELECTROCHEMICAL AND SOLID STATE LETTERS, 2003, 6 (10) :A218-A220
[10]   Structural and morphological moditications of a nanosized 62 atom percent Sn-Ni thin film anode during reaction with lithium [J].
Mukaibo, H ;
Momma, T ;
Mohamedi, M ;
Osaka, T .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2005, 152 (03) :A560-A565