Two levels of conformational pre-organization consolidate strong CH hydrogen bonds in chloride-triazolophane complexes

被引：60

作者：

Hua, Yuran ^{[1
]}

Ramabhadran, Raghunath O. ^{[1
]}

Karty, Jonathan A. ^{[1
]}

Raghavachari, Krishnan ^{[1
]}

Flood, Amar H. ^{[1
]}

机构：

[1] Indiana Univ, Dept Chem, Bloomington, IN 47405 USA

来源：

CHEMICAL COMMUNICATIONS | 2011年 / 47卷 / 21期

基金：

美国国家科学基金会;

关键词：

ANION RECEPTORS; ION-PAIRS; BINDING; CONTACTS; CL;

D O I：

10.1039/c1cc10428d

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Structural rigidity is verified as a pre-organizational factor that acts together with the macrocyclic effect such that synthesis helps in paying the cost of bringing together electropositive CH donors ready for H-bonding with chloride.

引用

页码：5979 / 5981

页数：3

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